might sound a bit obvious but is the pressure relief valve dripping or the pressure going right up when the heating is on? if not and you still can't find leak then you may have an internal leak and the water may be running down the condensate pipe. you can check by disconnecting the pipe when the boiler is off, and so not producing condensate, if you get water flowing out then there's the leak.
hope that helps.
Ian
March 2010